Zirconia sulfatada como un catalizador para la síntesis de biodiesel
DOI:
https://doi.org/10.29105/qh4.1-23Palabras clave:
Biodiesel, zirconia, microondasResumen
En este trabajo se sintetizaron nanopartículas de zirconia vía microondas, éstas se utilizaron como soporte de catalizadores sólidos. Se preparó hidróxido de zirconio por el método sol-gel a partir de propóxido de zirconio e hidróxido de amonio, una vez obtenido el gel se secó y se sometió a calentamiento por microondas y un enfriamiento rápido. La zirconia se sulfató con una solución de ácido sulfúrico y se utilizó como catalizador en la producción de biodiesel observando su actividad catalítica.
Las nanopartículas de zirconia obtenidas son de un tamaño de 50 a 60 nm con una mezcla de fases tetragonal y monoclínica, predominando la tetragonal, y un área superficial de 180.6 m2/g, esto se comprobó mediante difracción de rayos-X en polvos (DRX), microscopía electrónica de barrido (MEB) y la técnica Brunauer-Emmett-Teller (BET), uno de los logros principales fue que no se modificó el microondas y hubo mucho menos consumo de energía comparado con el método tradicional de calcinación, finalmente, se observó la conversión de aceite vegetal utilizado a biodiesel mediante la cromatografia de gases (CG), los rendimientos obtenidos son comparables con la sintesis de catálisis básica homogénea.
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Derechos de autor 2014 J. S. Acevedo, F. J. Garza-Méndez Garza-Méndez, E.M. Sánchez-Cervantes , J. Aguirre-Espinosa
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
