Síntesis y Caracterización de Películas Delgadas de Cu2ZnSnSe4
DOI:
https://doi.org/10.29105/qh11.01-276Palabras clave:
Película Delgada, depósito químico, brecha de energía, CZTSeResumen
Mediante el depósito secuencial de películas delgadas de SnSe (110 nm)-ZnSe (90 nm)-Cu2-xSe (55 nm) depositadas químicamente y con un post-tratamiento térmico en presencia de polvo de Selenio a 400 °C y 10 Torr se forma una película delgada de Cu2ZnSnSe4 de 205 nm de espesor. A partir de la medición de difracción de rayos X se comprueba la formación de la película delgada de Cu2ZnSnsSe4 sin la identificación de fases secundarias. El material tiene una brecha de energía de 0.84 eV, una conductividad eléctrica de 0.2 Ω^-1 cm^-1, con movlidad de huecos de 60 cm^2 V^-1 s^-1y concentración de portadores de huecos de 2 x10^16 cm^-3.
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-[1] Barrios Salgado Enue, Celdas Solares de películadelgada de seleniuros de metales por depósito químico.Tesis Doctoral. Universidad Nacional Autónoma deMéxico, Temixco, Morelos, mayo 2014.
-[2] T. K. Todorov, J. Tang, S. Bag, O. Gunawan, T.Gokmen, Y. Zhu, and D. B. Mitzi, “High-EfficiencySolar Cell with FEarth-Abundant Liquid-ProcessedAbsorber”, Adv. Energy Mater., 2012, 3, 34.
-[3] G. Zoppi, I. Forbes, R. W. Miles, P. J. Dale, J. J.Scragg and L. M. Peter, “Cu2ZnSnSe4 Thin Film SolarCells Produced by Selenisation of Magnetron SputteredPrecursors”, Prog. Photovolt: Res. Appl., 2009, 17, 315—319.
-[4] 1. L. Repins, M. J. Romero, J. V. Li, Su-Huai Wei,D. Kuciauskas, C-S Jiang, C. Beall, C. DeHart, J. Mann,W-C Hsu, G. Teeter, Al Goodrich, and R. Noufi,“Kesterite Successes, Ongoing Work, and Challenges: A Perspective From Vacuum Deposition”, IEEE J. Photovoltaics, 2013, 3, 439.
-[5] H. Katagiri, K. Saitoh, T. Washio, H. Shinohara, T. Kurumadani, S. Miyajima, Develoment of thin film solar cell based on Cu2ZnSnS4. Sol. Energy Mater. Sol. Cells 65 (2001) 141-148. DOI: https://doi.org/10.1016/S0927-0248(00)00088-X
-[6] M. Ganchev, L. Kaupmees, J. Iliyna, J. Raudoja, O.Volobujeva, H. Dikov, M. Altosaar, E. Mellikov,T.Varem, Formation of Cu2ZnSnSe4 thin films by selenization of electrodeposited stacked binary alloy layers, Energy Procedia 2 (2010) 65—70 DOI: https://doi.org/10.1016/j.egypro.2010.07.012
-[7] T. Tanaka, T. Nagatomo, D. Kawasaki, M. Nishio, Q. Guo, A. Wakahara, et al., Preparation of Cu2ZnSnS4 thin films by hybrid sputtering, Journal of Physics and Chemistry of Solids 66 (2005) 1978-1981. DOI: https://doi.org/10.1016/j.jpcs.2005.09.037
-[8] A. Redinger, D. M. Berg, P. J. Dale, R. Djemour, L. Gitay, T. Eisenbarth, N. Valle, S. Siebentritt, Route to wards high-efficiency single-phase Cu2ZnSn(S,Se)4 thin-film solar cells: model experiments and literature review, IEEE Journal of Photovoltaics 1 (2011) 200. DOI: https://doi.org/10.1109/JPHOTOV.2011.2168811
-[9] S. Abermann, “Non-vacuum processed next generation thin film photovoltaics: Towards marketable efficiency and production of CZTS based solar cells”, Solar Energy, 2013, 94, 37-70.
-[10] S. Schorr, “The crystal structure of kesterite type compounds: A neutron and X-ray diffraction study ”, Sol. Energy Mater. 8 Sol. Cells, 2011, 95, 1482-1488.
-[11] J. J. Scragg, T. Ericson, T. Kubart, M. Edoff, C. Platzer-Bjorkmann, “Chemical Insights into the Instability of Cu2ZnSnS4 Films during Annealing”, Chem. Mater., 2011, 23, 4625.
-[12] E. Barrios-Salgado, M. T. S. Nair, and P. K. Nair, ECS J. Solid State Sci. Technol., 2014, 3, Q169-Q175.
-[13] C. A. Estrada, P. K. Nair, M. T. S. Nair, R. A. Zingaro and E. A. Meyers, Chemical bath deposition of ZnSe and CuSe thin films using N,N-dimethylselenourea, J. Electrochem. Soc., 1994, 75, 1557-1564.
-[14] V. M. Garcia, M. T. S. Nair, and P. K. Nair, Copper selenide thin films by chemical bath deposition, J. Cryst. Growth, 1999; 203, 113-124.
-[15] J. W. Earley, Description and synthesis of theselenide minerals, Am. Mineral. 1950; 337-364.
-[16] J. S. King, S. M. Herron, B. P. Tran, K. PanganOkimoto, and S. F. Bent, "Aqueous bath process for deposition of Cu2ZnSnS4 photovoltaic absorbers," A. Wangperawong, , Thin Solid Films, 2011, 519, 2488—2492.
-[17] V. M. García, Películas delgadas de selenuros metálicos (Bi, Cd, Cu y Zn) por depósito químico y tratamientos postdepósito para aplicaciones fotovoltaicas, Doctorado en Ciencias (Ciencia de Materiales), Facultad de Ciencias, UNAM (1998).
-[18] C. S. Barrette, T. M. Masalski, Structure ofMetals, McGraw Hill, New York (1966) 668.
-[19] P. M. P. Salomé, P. A. Fernandes, A. F. da Cunha, Morphological and structural characterization of Cu2ZnSnSe4 thin films grown by selenization of elemental precursor layers, Thin Solid Films 517 (2009)2531-2534.
-[20] J. Sunghun, G. Jihye, H. Y. Jae, J. A. Se, N. Dahyun, C. Hyeonsik, A. Seungkyu, C. Ara, S. S. Kee, H. Y. Kyung, Cu2ZnSnSe4 thin film solar cells based on a single-step co-evaporation process, Thin Solid Films 535 (2013) 52-56. DOI: https://doi.org/10.1016/j.tsf.2012.10.082
-[21] P. M. P. Salomé, P. A. Fernandes, A. F. da Cunha, Morphological and structural characterization of Cu2ZnSnSe4 thin films grown by selenization of elemental precursor layers, Thin Solid Films 517 (2009) 2531-2534. DOI: https://doi.org/10.1016/j.tsf.2008.11.034
-[22] K. Dong-Hau, H. Jen-Pin, Development of theCu2ZnSnSe4 absorption layer with “passivated” largegrains for a thin-film solar cell device, Journal of Crystal Growth 372 (2013) 34-38. DOI: https://doi.org/10.1016/j.jcrysgro.2013.03.013
-[23] W. Septina, S. Ikeda, A. Kyoraiseki, T. Harada, M. Matsumura, Single-step electrodeposition of a microcrystalline Cu2ZnSnSe4 thin film with a kesterite structure, Electrochimica Acta 88 (2013) 436- 442.
-[24] W. Septina, S. Ikeda, A. Kyoraiseki, T. Harada, M. Matsumura, Single-step electrodeposition of a microcrystalline Cu2ZnSnSe4 thin film with a kesterite structure, Electrochimica Acta 88 (2013) 436- 442. DOI: https://doi.org/10.1016/j.electacta.2012.10.076
-[25] S. Chen, X. G. Gong, A. Walsh, and S. H. Wei, Crystal and electronic band structure of Cu2ZnSnX4 (X=S and Se) photovoltaic absorbers: First-principles insights. Applied Physics Letters 94 (2009) 041903. DOI: https://doi.org/10.1063/1.3074499
-[26] C. Persson, Electronic and optical properties of Cu2ZnSnS4 and Cu2ZnSnSe4, Journal of Applied Physics 107 (2010) 053710.
-[27] G. Zoppi, I. Forbes, R. W. Miles, P. J. Dale, J. J. Scragg and L. M. Peter, Cu2ZnSnSe4 thin film solar cells produced by selenization of magnetron sputtered precursors, Prog. Photovolt: Res. Appl. 2009, 17, 315- 319.
-[28] S. Jung, J. Gwak, J. H. Yun, S. Ahn, D. Nam, H. Cheong, S. Ahn, A. Cho, KS Shin, KH Yoon, Cu2ZnSnSe4 thin film solar cells based on a single-step co-evaporation process, Thin Solid Films, 2013, 535, 52- 56.
-[29] P. Uday Bhaskar, G. Suresh Babu, Y.B. Kishore Kumar, V. Sundara Raja. Growth and characterization of Cu2ZnSnSe4 thin films by a two-stage process, Solar Energy Materials £ Solar Cells 115 (2013) 181-188. DOI: https://doi.org/10.1016/j.solmat.2013.03.017
-[30] O. Volobujeva, S. Bereznev, J. Raudoja, K. Otto, M. Pilvet, E. Mellikov, Synthesis and characterisation of Cu2ZnSnSe4 thin films prepared via a vacuum.
-[31] G. Qijie, M. Grayson, W. C. Yang, C. W. Bryce, A.S. Eric, W. H. Hugh, and A. Rakesh, Fabrication 0f 7.2% Efficient CZTSSe Solar Cells Using CZTS Nanocrystals. J. 10.1021/a108427b XXXX American Chemical Society.