Estudio y análisis de la degradación un herbicida triazinico por procesos de oxidación avanzada en sistemas acuosos
DOI:
https://doi.org/10.29105/qh13.03-441Palabras clave:
Catálisis, Electrofenton, Herbicida, ElectrofotofentonResumen
Se utilizaron nanopartículas de Fe3+ /Fe2+ para el análisis de la degradación de atrazina empleando POAs acoplado a electrocatálisis, el tamaño de las nanopartículas es de alrededor de 10 hasta 50 nm. Para los estudios de la cinética de degradación de la atrazina grado analítico obteniendo para el proceso fenton (6 mg L-1), fotofenton (9 mg L-1), electrofenton (18 mg L-1) y electrofotofenton (78 mg L-1) de degradación respectivamente. Además de que se desarrolló un método analítico para la cuantificación de los productos de degradación por cromatografía de líquidos.
Descargas
Citas
- [1].Viegas, C.A.; Silva, V.P.; Varela, V.M.; Correia, V.; Ribeiro, R.; Moreira-Santos, M. (2019). Evaluating formulation and storage of Arthrobacter aurescens strain TC 1 as a bioremediation tool for terbuthylazine containinated soils: Efficacy on abatement of aquatic ecotoxicity. dci. Total En viron. 668, 714-722. DOI: https://doi.org/10.1016/j.scitotenv.2019.02.355
- [2]. Patel, D., Toliwal, S.D., Patel, J.V., Jadav, K., Gupte, A., Patel, Y. (2011). Studis on microwave assisted synthesis of triazines from byproducts ofoil processing industries. J. Appl. Chem. Res. 16, 53-60.
- [3]. Schulz, R.; Bub, S.; Petschick, L.L.; Stehle, S.; Wolfram, J. (2021). Applied pesticide toxicity shifts toward plants and invertebrates, even in GM crops. Science, 372, 81—84. DOI: https://doi.org/10.1126/science.abe1148
- [4]. Douglas, M. R. & Tooker, J. F. (2015). Large-scale deployment of seed treatments has driven rapid increase in use of neonicotinoid insecticides and preemptive pest management in US field crops. En viroilmental Science& Technology 49, 5088-5097. DOI: https://doi.org/10.1021/es506141g
- [5]. Stenoien, C. et al. Monarchs in decline:a collateral landscapelevel efect of modem agriculture. (2018). Insect Science 25, 528—541, https.//doi.org/10. 1111/1744-7917.12404. DOI: https://doi.org/10.1111/1744-7917.12404
- [6]. Comisión Federal para la Protección contra Riesgos Sanitarios (2021). Consulta de Registros Sanitarios de Plaguicidas, Nutrientes Vegetales y LMR. México. http://siipris03.cofepris.gob.rex/Resoluciones/Consultas/Con WebRegP1aguicida.asp
- [7]. Gibbs, K. E., Mackey, R. L. & Currie, D. J. (2009). Human land use, agriculture, pesticides and losses of imperiled species. Diversity and Distriburtons 15, 242-253. DOI: https://doi.org/10.1111/j.1472-4642.2008.00543.x
- [8]. Huseth, A. S., Chappell, T. M., Chitturi, A., Jacobson, A. L. & Kennedy, G. G. (2018). Insecticide resistance signals negative consequences of widespread neonicotinoid use on multiple feld crops in the US cotton belt. Environmental Science & Technology . 52, 2314-2322. DOI: https://doi.org/10.1021/acs.est.7b06015
- [9]. Malakootian, M., Shahesinaeili, A., Faraji, M ., Amiri, H.,& Silva Martinez, S. (2019). Advanced oxidation processes for the removal of organophosphorus pesticides in aqueous matrices:A systematic review and meta-analysis. Process Safety and Environmental Protection. doi: 10.1016/j.psep.2019.12.004 DOI: https://doi.org/10.1016/j.psep.2019.12.004
- [10]. Ainiri, H., Nabizadeh, R., Silva Martinez, S., Jamaleddin Shahtaheri, S., Yaghmaeian, K.,Badiei, A., Nazmara, S., Naddafi, K., (201 8). Response surface methodology modeling to improve degradation of Chlorpyrifos in agriculture runoff using TiO2 solarphotocatalytic in a raceway pond reactor. Eecotoxicol. Enviroit. Saf. 147, 919-925. DOI: https://doi.org/10.1016/j.ecoenv.2017.09.062
- [11]. Mirmasoomi, S.R., Mehdipour Ghazi, M., Galedari, M., (2017). Photocatalytic degra-dation of diazinon under visible light using TiO2/Fe2O3 nanocompositesynthesized by ultrasonic-assisted impregnation method. Sep. Purif Technol. 175,4 18—427. DOI: https://doi.org/10.1016/j.seppur.2016.11.021
- [12]. Ram, M., Shanker, U., (2018). Effective adsorption and enhanced degradation of var-ious pesticides from aqueous solution by Prussian blue nanorods. J. Em viron. Chem. Errg. 6, 1512—1521. DOI: https://doi.org/10.1016/j.jece.2018.01.060
- [13]. Li, W., Liu, Y., Duan, J., van Leeuwcn, J., Saint, C. P., (20 15). UV and UV/H2O2 treatment of diazinon and its influence on disinfection byproduct formation followingchlorination. Chem. Eiig. J. 274, 39—49. DOI: https://doi.org/10.1016/j.cej.2015.03.130
- [14]. Rajendran, S., Palani, G.,S hanmugam, V.,Trilaksanna, H., Kannan, K.,N ykiel, M., ...& Marimuthu, U.(2023).A review of synthesis and applications of Al2O3 fororganic dye degradation/adsorption. Molecules, 28(23), 7922. DOI: https://doi.org/10.3390/molecules28237922
- [15]. Abbasi, S. (2023). Magnetic photocatalysts based on graphene oxide: synthesis, characterization, application in advanced oxidation processes and response surface analysis. Applied Water Science, 13(6),1 28. DOI: https://doi.org/10.1007/s13201-023-01931-4
- [16]. Hiep, H., Tuan Anh, P., Dao, V. D.,& Viet Quang, D. (2023). Greener method for the application of TiO2 nanoparticles to remove herbicide in water. Journal of Analytical Methods in Chemistiy, 2023(1), 3806240. DOI: https://doi.org/10.1155/2023/3806240
- [17]. Surendra, B., Guduru, N.,Joshua, M. S., Kiran, B. R.,& Vangalapati, M. (2023). Influence of chemically synthesized TiO2 nanoparticles for photocatalytic degradation of herbicide atrazine. Materials Today. Proceedings. DOI: https://doi.org/10.1016/j.matpr.2023.09.058
- [18]. Kim, C., Ahn, J., Kim, T., Hwang, I. (2019). Mechanisms of electro-assisted persulfate/nano-Fe' oxidation process: Roles of redox mediation by dissolved Fe. Journal of Hazardous Materials, 121739. doi:10.1016/j.jhazmat.2019.121739 DOI: https://doi.org/10.1016/j.jhazmat.2019.121739
Descargas
Publicado
Cómo citar
Número
Sección
Licencia
Derechos de autor 2025 Rossy Feria Reyes, Alicia Soledad Martínez Silva, Aldo Eleazar Pérez Ramos, Luis Humberto Robledo Taboada, Héctor Ramón Azcaray Rivera, Eric Mario Silva Cruz
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
