Inorganic Electrosynthesis: a Green Chemical Method for tin Complexes
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https://doi.org/10.29105/qh1.3-224Keywords:
Electrosynthesis, Green, Method for tin ComplexesAbstract
SnIV complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 1H and 13C-NMR, IR, and high resolution mass spectrometry. However, all were not enough soluble in organic solvent in order to record its 119Sn-NMR spectra, this unusual behavior was attributed to the polymeric association thought intermolecular coordination OSn.
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Copyright (c) 2011 Víctor Manuel Jiménez Pérez , Blanca M. Muñoz Flores , Boris I. KHARISOV, Eugenio Hernández Fernández , Susana López Cortina, Noemí AKSMAN, Rosalba Ramírez Durón
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