Cation Xanthated Exchangers from Colombian Sub-Bituminous Coals Effectively Removed Cadmium and Lead from Aqueous Solutions

Authors

  • Lewis Gómez-De-Arco Universidad de Cartagena
  • Liliana Alzate-Rodríguez Universidad de Cartagena
  • Fredy Colpas-Castillo Universidad de Cartagena
  • Roberto Fernández-Maestre Universidad de Cartagena

DOI:

https://doi.org/10.29105/qh2.1-89

Keywords:

subbituminous coal, cation exchange, exchangers xanthates

Abstract

In Colombia, low rank coals are almost totally used for power and metallurgical aims, which are activities that produce contamination. In this investigation, as an altemative to the traditional use of low rank coals, we prepared cationic xanthated exchangers from a subbituminous coal (67.6% C, 4.6% H, 22.4% O, 0.6% S, 3.2% ashes and 46.2% volatile matter) of Montelibano-Córdoba; this exchanger showed better exchange capacities for cadmium and lead (1.8 meq/g) than traditional sulphonated exchangers (0.56 and 1.11 meq/g for cadmium and lead respectively). Xanthation was verified at 30 ºC and at 5-10 ºC with NaOH and CS2. Toe best performance of xanthation, determined by Infrared spectrometry and ion exchange experiments, occurred at low temperatures maybe due to CS2 volatility. By diminishing the particle size of coal the exchange capacity increased. The exchange capacity was evaluated by flame atomic absorption spectrometry.

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Author Biographies

Lewis Gómez-De-Arco, Universidad de Cartagena

Grupo de Carboquímica

Liliana Alzate-Rodríguez, Universidad de Cartagena

Grupo de Carboquímica

Fredy Colpas-Castillo , Universidad de Cartagena

Grupo de Carboquímica

Roberto Fernández-Maestre, Universidad de Cartagena

Grupo de Carboquímica

References

-[1] World Coal Association, http://www.worldcoal.org/coal/coalmining/. Accessed in October 22/2011.

-[2] R.A.K. Rao, M.A. Khan, F. Rehman, Adsorp. Sci. Technol. 29 (2011) 83. DOI: https://doi.org/10.1260/0263-6174.29.1.83

-[3] M. Halina, A. Danuta, Fuel 70 (1991)551. DOI: https://doi.org/10.1016/0016-2361(91)90035-9

-[4] K. Murakami, Fuel 43 (1994)95. DOI: https://doi.org/10.1016/0378-3820(95)00009-V

-[5] K. Murakami, T. Yamada, K. Fuda, T. Matsunaga, Y. Nishiyama, Fuel 76,(1997) 1085. DOI: https://doi.org/10.1016/S0016-2361(97)00126-9

-[6] J. Rivera, et al. Memorias del Congreso Nacional de Ciencias y Tecnología del Carbón. Paipa, Colombia, 1998.

-[7] C.L. Swanson, T.R. Naffziger, C.R. Russell, B.T. Hofreiter, C.E. Rist, Ind. Eng. Chem. Prod. Res. Dev. 3 (1964) 22. DOI: https://doi.org/10.1021/i360009a008

-[8] E. Marañón, H. Sastre, Biores. Technol. 40 ( 1992) 73. DOI: https://doi.org/10.1016/0960-8524(92)90122-E

-[9] E. Marañón, H. Sastre. React. Polym. 18(1992) 173. DOI: https://doi.org/10.1016/0923-1137(92)90256-2

-[10] J. Anwar, U. Shafique, M.Salman, Waheed-uz Zaman, S. Anwar, J.M. Anzano, J. Hazard Mater. 171 (2009) 797. DOI: https://doi.org/10.1016/j.jhazmat.2009.06.076

-[11] G. Arslan, E. Pehlivan, Bioresour Technol. 98 (2007) 2836. DOI: https://doi.org/10.1016/j.biortech.2006.09.041

-[12] C. Arpa, E. Basyilmaz, S. Bektas, ó. Gene, Y. Yürüm, Fuel Process. Technol. 68, (2000) 111. DOI: https://doi.org/10.1016/S0378-3820(00)00126-0

-[13] A.D. Stuart, Fuel 65 (1986) 1003. DOI: https://doi.org/10.1016/0016-2361(86)90212-7

-[14] H.N.S. Schafer, Fuel 49 (1970) 197. DOI: https://doi.org/10.1016/0016-2361(70)90040-2

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Published

2011-12-31

How to Cite

Gómez-De-Arco, L. ., Alzate-Rodríguez, L., Colpas-Castillo , F. ., & Fernández-Maestre, R. . (2011). Cation Xanthated Exchangers from Colombian Sub-Bituminous Coals Effectively Removed Cadmium and Lead from Aqueous Solutions . Quimica Hoy, 2(1), 23–25. https://doi.org/10.29105/qh2.1-89